Occupational exposure limits component source type value note ethyl alcohol us acgih stel ppm. Material safety data sheet isopropyl alcohol coleparmer. None of the alkyl isocyanates were as suitable as phenyl isocyanate. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Msds 3,3dimethyl2butanol, 99% cas 464073 msds tert. Safety data sheet 1,1,2,2tetraphenylethane1,2diol page. Gb is odorless and is the most volatile nerve agent.
Composition information ingredient cas no proportion ethanol 64175 70% vv macadamia oil 12849201 msds and with local authorities. Pinacolone 3,3dimethyl2butanone is an important ketone in organic chemistry. Army soldier and biological chemical command sbccom. I suspect this is a set question, but if you are remotly interested in doing this i suggest you use the magnesiummagnesium iodide method to make the pinacol rather than the magnesium amalgam method. A novel gaseous pinacolyl alcohol sensor utilizing cataluminescence on alumina nanowires prepared by supercritical fluid drying. Click on any of the following chemicals below to download the msds sheet. Sciencemadness discussion board pinacolyl alcohol and. One reagent lane fair lawn, nj 07410 for information in north america, call.
For small incipient fires, use media such as alcohol foam, dry chemical, or carbon dioxide. It is a colourless liquid that is slightly soluble in water 2 ml100 ml h 2 o, but miscible with most organic solvents. Sbccom online site search data lewisite poiso date. Empty containers pose a fire risk, evaporate the residue under a fume hood. It is a precursor to triazolylpinacolone in the synthesis of the fungicide triadimefon and in synthesis of the herbicide metribuzin. Use alcohol resistant foam or flood with fine water spray. Sigmaaldrich offers a number of isopropyl alcohol products. Material safety data sheet msds isopropyl alcohol product identification product name.
He prepared it by the reaction of sodium hypochlorite with picric acid. Chloropicrin, also known as ps and nitrochloroform, is a chemical compound currently used as a broadspectrum antimicrobial, fungicide, herbicide, insecticide, and nematicide. Where there is any possibility that an employees eyes and or skin may be exposed to. It is a colorless liquid and has a slight peppermint or camphor odor. Acute tests were conducted on pimephales promelas, 48 hr ec50 443. In rats it is suggested that pinacolyl alcohol is metabolised by alcohol dehydrogenase with the major metabolite being pinacolone james et al, 1987.
The peaks of the chromatogram were conclusive in determining and confirming our hypothesis of the production. For large fires, apply water from as far as possible. Remove from source of exposure and get medical attention for any breathing difficulty. Be careful that the product is not present at a concentration level above tlv. Hazards from combustion products toxic andor irritating fumes including carbon monoxide and carbon dioxide may be emitted. Exposure controls personal protection control parameters, e. Nerve agents ga, gb, gd soman, and vx are manufactured compounds. Different types of alcohols may dehydrate through a slightly different mechanism pathway.
Our team of scientists has experience in all areas of research including life science, material science, chemical synthesis, chromatography, analytical and many others. This ion acts as a very good leaving group which leaves to form a. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Immediate effects can be expected after shortterm exposure. Structure, properties, spectra, suppliers and links for. Safety data sheet molecular weight not applicable chemical name cas number % by weight silica gel 7631869 proprietary cellulose 9004346 proprietary sodium lauryl sulfate 1512 1 composition there are no additional ingredients present which, within the current knowledge of the supplier and in the. Do not induce vomiting if patient is unconscious or extremely drowsy. Details of manufacturer or importer manufacturer glaxosmithkline australia phamaceuticals and vaccines 1061 mountain highway melbourne, victoria 3155 australia general information phone number normal business hours. Application 3,3dimethyl2butanol pinacolyl alcohol can be used as a substrate. In general higher yields were obtained using the acetonitrile1 m hcl method, in many cases giving the boronic acids 2 in 90% yield. Section 1 chemical product and company identification. This one is more obvious than it looks from the structure.
In such cases chromatography was unnecessary, and simple removal of the solvent after filtration provided. In such cases chromatography was unnecessary, and simple removal of the solvent after filtration provided the nearpure boronic acid with only a trace of. Its chemical structural formula is cl 3 cno 2 synthesis. This page contains pharmcos material safety data sheets. Aquatic species the aquatic toxicity of a secondary alcohol, 3,3dimethyl2butanol pinacolyl alcohol pa, was determined. The peaks of the chromatogram were conclusive in determining and confirming our hypothesis of. Firefighting measure suitable extinguishing media use dry chemical, alcohol stable foam, carbon dioxide or fog type extinguishers. Recommended use restrictions on use no other uses are advised. To study the oxidation of secondary alcohols to ketones using cyclic microwave heating technique. Msds is from available published sources and is believed to be accurate.
Various aryl pinacolyl boronate esters 1 were then deprotected using these conditions, as shown in table 2. Composition information ingredient cas no proportion ethanol 64175 70% vv macadamia oil 12849201 alcohol gel issue no. Use very large quantities flooding of water applied as a mist or spray. Analysis of the mechanism of asymmetric amplification by chiral auxiliary trans1,2diaminocyclohexane bistriflamide. It occurs widely in nature, being found in a variety of essential oils. Indication of any immediate medical attention and special treatment needed. Pinacolyl alcohol is a common name for 3,3dimethyl2butanol, also known as pine alcohol. Material safety data sheet methyl acetate section 1 chemical product and company identification msds name. When clicked the sheets are downloaded to your harddrive in a.
Other information msds first issued 28032007 classification and labelling have been performed according to eu directives 67548eec, 88379eec, including amendments and the intended use. Growth inhibition tests 96 hr were conducted using ankistrodesmus falcatus, ec50 257. There may be irritation of the throat with a feeling of tightness in the chest. India veritas house, 70 mint road, fort, mumbai 400 001. Pinacolyl alcohol appears on the list of schedule 2 substances cwc as a precursor for the nerve agent soman. Cool all affected containers with flooding quantities of water. The impact of humidity, temperature and ultraviolet light. Mechanism for the dehydration of alcohol into alkene.
Sigmaaldrich material safety data sheet product name. Employee must wear splashproof or dustresistant safety goggles to prevent eye contact with this substance emergency wash facilities. Cool containers with water spray until well after the fire is out. A mixture of benzyl alcohol and 58% sulfuric acid decomposed violently when heated to 180c. Material safety data sheet isopropyl alcohol, 50100% vv section 1. The statements contained herein are based upon technical data that nicepak products, inc. Pinacolyl alcohols molecular formula is c 6 h 14 o and is a secondary alcohol. June 1, 2001 aaper alcohol and chemical company 1101 isaac shelby drive, p. Alcohols can now be analyzed by a direct analysis in real. Aug 23, 2004 various aryl pinacolyl boronate esters 1 were then deprotected using these conditions, as shown in table 2. Safety data sheet according to federal register vol.
Pinacolyl alcohol chemical information, properties, structures, articles, patents and more chemical data. Pinacolyl alcohol appears on the list of schedule 2 substances cwc as. Azer scientific inc 701 hemlock road morgantown pa 19543 610. Move container from fire area if it can be done without risk. Alkenes from dehydration of alcohols chemistry libretexts. Phenethyl alcohol, or 2phenylethanol, is the organic compound that consists of a phenethyl group c 6 h 5 ch 2 ch 2 group attached to oh. The user must determine suitability of this information for his application. Discontinue use if skin irritation and redness develop. These files can be easily viewed in adobe acrobat reader. No warranty, express or implied, is made and qorpak assumes no liability resulting from the use of this msds. Ga has a slightly fruity odor, and gd has a slight camphorlike odor. Chloropicrin was discovered in 1848 by scottish chemist john stenhouse. Pinacolyl alcohol s molecular formula is c 6 h 14 o and is a secondary alcohol.
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